Brilliant black (Black PN)
2519-30-4 · 1743 Black · 2WPR32U0CP · ACID BLACK 3 (NAPHTHOL BLACK C.I. 27260) · AGKKBBSOKGLVTM-HZGWVLLFSA-J · Black BN · Black PN · Black PN (~80%) · Black PN (~80per cent) · black-pn · Blue Black BN · Brillant Black 1 · Brilliant Acid Black BN Extra Pure A · Brilliant Acid Black BNA Export · Brilliant Black · BRILLIANT BLACK (BLACK PN) · Brilliant black 1 · Brilliant Black A · Brilliant Black BN · Brilliant Black N. FQ · Brilliant Black NAF · Brilliant Black PN · BRILLIANTBLACKBN · Brilliantschwarz BN · C.I. FOOD BLACK 1 · C.I. Food Black 1, tetrasodium salt · C.I. Food Black-1 · CCRIS 113 · CERN brilantni PN [Czech] · CERN potravinarska 1 [Czech] · Certicol Black PNW · CI Food Black 1 · Cilefa Black B · COLOUR INDEX NO. 28440 · E 151 · E151; Brilliant Black BN (E151) · Edicol Supra Black BN · Food black 1 · Hexacol Black PN · INS NO.151 · INS-151 · L Black 8000 · L-Schwarz 1 · Melan Black · Noir brillant BN · XYLENE BLACK · Xylene Black F · E151 · 151 · 1,7-Naphthalenedisulfonic acid, 4-(acetylamino)-5-hydroxy-6-((7-sulfo-4-((4-sulfophenyl)azo)-1-naphthalenyl)azo)-, tetrasodium salt · 1,7-Naphthalenedisulfonic acid, 4-acetamido-5-hydroxy-6-((7-sulfo-4-((p-sulfophenyl)azo)-1-naphthyl)azo)-, tetrasodium salt · 2-(4-(p-Sulfophenylazo)-7-sulfo-1-naphthylazo)-8-acetamido-1-naphthol-3,5-di-sulonic acid, tetrasodium salt · Sodium 4-acetamido-5-hydroxy-6-((7-sulfonato-4-((4-sulfonatophenyl)diazenyl)naphthalen-1-yl)diazenyl)naphthalene-1,7-disulfonate · Tetrasodium 1-acetamido-2-hydroxy-3-(4-((4-sulphonatophenylazo)-7-sulphonato-1-naphthylazo))naphthalene-4,6-disulphonate · tetrasodium 4-(acetylamino)-5-hydroxy-6-[(E)-{7-sulfonato-4-[(E)-(4-sulfonatophenyl)diazenyl]naphthalen-1-yl}diazenyl]naphthalene-1,7-disulfonate · Tetrasodium;(6E)-4-acetamido-5-oxo-6-[[7-sulfonato-4-[(4-sulfonatophenyl)diazenyl]naphthalen-1-yl]hydrazinylidene]naphthalene-1,7-disulfonate · tetrasodium;4-acetamido-5-hydroxy-6-[[7-sulfonato-4-[(4-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,7-disulfonate · Brilliant Black PN · Brilantná čierna PN · Brilantní čerň PN · Briliantinis juodasis BN · BRILIANTINIS JUODASIS PN · Briljanta melnais PN · Briljantmust PN · briljantno črno PN · Briljantsvart PN · Briljanttimusta PN · Briljantzwart PN · Brillantschwarz PN · Brilliant Black PN · Brilliánsfekete PN · Czerń brylantowa PN · Iswed Brillanti PN · Negro brilhante PN · Negro brillante PN · Negru briliant PN · Nero brillante PN · Noir brillant PN · ΛΑΜΒΡΟ ΜΑΥΡΟ PN · Λαμπρό μαύρο PN · Брилянтно черно PNE number E151INS 151CAS 2519-30-4
Listed as a colour by Codex and the EU.
Listed as colours (EU, Codex)
- European Union: Colours — Regulation (EC) No 1333/2008, Annex II, Part B, 1. Colours (consolidated text 02008R1333-20260818)
- Codex Alimentarius: Colour — CXS 192-1995 Table One, INS 151

Brilliant Black PN is a synthetic black dye used in sauces, preserved fish and confectionery, usually to deepen other colours rather than on its own.
Where it is and isn’t permitted
| Jurisdiction | Status | Scope and limits | Citation |
|---|---|---|---|
| Australia and New Zealand | Permitted, with conditions | 44 food categories Show every food category
| Food Standards Code, Schedule 15, S15—5and 43 further provisionsretrieved 2026-10-17 |
| Canada | No listing matchedHealth Canada’s lists name additives without E or INS numbers, so this site matches them by exact name. A substance listed there under a name this site does not recognise has no row here. | ||
| European Union | Permitted, with conditions | 25 food categories highest permitted level 500 mg/l Show every food category
| Regulation (EC) No 1333/2008, Annex IIand 24 further provisionsretrieved 2026-10-18 |
| Great Britain | Permitted, with conditions | 34 food categories highest permitted level 500 mg/kg or mg/l Show every food category
| Assimilated Regulation (EC) No 1333/2008and 33 further provisionsretrieved 2026-10-18 |
| Japan | No listing matchedThis site imports only Japan’s list of designated additives (Appended Table 1 to the Regulations for Enforcement of the Food Sanitation Act), matched by English name. Existing additives, natural flavouring agents and ordinary foods used as additives are permitted outside that list and are not imported, so an empty row does not show that Japan does not permit the substance. | ||
| South Korea | No listing matchedThis site imports Part III of South Korea’s Standards and Specifications for Food Additives, matched by CAS number, then INS number, then exact name. Mixed preparations and sanitisers are not imported, and an entry whose identifiers disagreed with a page’s is held for review, so an empty row does not show that South Korea does not permit the substance. | ||
| United States | Not listedDoes not appear on this jurisdiction’s permitted list. That is not the same as being prohibited. | ||
| Codex Alimentarius | Permitted, with conditions | 29 food categories highest permitted level 530 mg/kg Show every food category and its notes
| CXS 192-1995 Table One, INS 151and 28 further provisionsretrieved 2026-09-07 |
How much is permitted
A listing usually limits the quantity as well as the food. Only one of the forms that takes is a figure: quantum satis and good manufacturing practice permit the amount the technological effect requires and no more, which is a limit rather than the absence of one. Figures below are the range across every food category this page is listed in, and categories differ between regulators — see how much is permitted.
| Australia and New Zealand | — | 44 no quantity stated |
|---|---|---|
| European Union | 50 mg/kg – 500 mg/kg | 24 numeric limit, 1 quantum satis |
| Great Britain | 50 mg/kg – 500 mg/kg | 28 numeric limit, 5 several limits, 1 quantum satis |
| Codex Alimentarius | 10 mg/kg – 530 mg/kg | 29 numeric limit |
What it is made from
A tetrazo dye built from petroleum-derived aromatic intermediates through two successive diazotisation and coupling steps.
- Vegan
- Vegetarian
Compare other additives on the dietary indexes.
- CAS registry number
- 2519-30-4
- InChIKey
- GMMAPXRGRVJYJY-UHFFFAOYSA-J
- PubChem
- CID 17293
The two specifications, compared
The European Union sets identity and purity by regulation; JECFA publishes its own through FAO, advisory until a country adopts it. Both documents are below in full. These are the parameters each puts a number on.
| Parameter | European Union | JECFA |
|---|---|---|
| Assay | no less than 80 % | no less than 80 % |
| Lead | no more than 2 mg/kg | no more than 2 mg/kg |
| Arsenic | no more than 3 mg/kg | — |
| Mercury | no more than 1 mg/kg | — |
| Cadmium | no more than 1 mg/kg | — |
The two documents state the same figures for every parameter compared here.
How the EU defines it
The legal specification an additive must meet to be sold as this E number in the EU — what it is, how it may be made, and the purity it must reach. From Commission Regulation (EU) No 231/2012.
E 151 Brilliant black pn
Brilliant Black PN consists essentially of tetrasodium-4-acetamido-5- hydroxy-6-[7-sulfonato-4-(4-sulfonatophenylazo)-1-naphthylazo] naphthalene-1,7-disulfonate and subsidiary colouring matters together with sodium chloride and/or sodium sulphate as the principal uncoloured components. Brilliant Black PN is described as the sodium salt. The calcium and the potassium salt are also permitted.
Synonyms: CI Food Black 1
Assay, identification and purity criteria
Description and assay
- Colour Index No
- 28440
- Einecs
- 219-746-5
- Chemical name
- Tetrasodium 4-acetamido-5-hydroxy-6-[7-sulfonato-4-(4-sulfonatophenylazo)-1-naphthylazo] naphthalene-1,7-disulfonate
- Chemical formula
- C₂₈H₁₇N₅Na₄O₁₄S₄
- Molecular weight
- 867,69
- Assay
- Content not less than 80 % total colouring matters calculated as the sodium salt [image] 530 at ca. 570 nm in solution
- Description
- Black powder or granules
- Appearance of the aqueous solution
- Black-bluish
Identification
- Spectrometry
- Maximum in water at ca. 570 nm
Purity criteria
- Water insoluble matter
- Not more than 0,2 %
- Subsidiary colouring matters
- Not more than 4 % (expressed on the dye content)
- 4-acetamido-5-hydroxynaphthalene-1,7-disulfonic acid
- [image] | Total not more than 0,8 % 4-amino-5-hydroxynaphthalene-1,7-disulfonic acid 8-aminonaphthalene-2-sulfonic acid 4,4′-diazoaminodi-(benzenesulfonic acid)
- Unsulfonated primary aromatic amines
- Not more than 0,01 % (calculated as aniline)
- Ether extractable matter
- Not more than 0,2 % under neutral conditions
- Arsenic
- Not more than 3 mg/kg
- Lead
- Not more than 2 mg/kg
- Mercury
- Not more than 1 mg/kg
- Cadmium
- Not more than 1 mg/kg
How JECFA defines it
The international specification for identity and purity, prepared by the Joint FAO/WHO Expert Committee on Food Additives and published by FAO. It is a different document from any above, written by a different body and revised on its own cycle; it is advisory, and a country adopts it or does not.
INS 151 Brilliant Black PN
Brilliant Black PN consists of tetrasodium 4-(acetylamino)-5-hydroxy-6-[2-[7-sulfo-4-[2-(4-sulfophenyl)2pprox.2]-1-naphthalenyl]2pprox.2]-1,7-naphthalenedisulfonate and subsidiary colouring matters, as well as sodium chloride and/or sodium sulfate as the principal uncoloured components. Brilliant Black PN is manufactured by diazotizing 4-aminobenzenesulfonic acid (sulfanilic acid), coupling with 8-aminonaphthalene-2-sulfonic acid (1,7-Cleve’s acid), diazotizing the product, and coupling with 4-(acetylamino)-5-hydroxy-1,7-naphthalenedisulfonic acid (N-acetyl K acid). Brilliant Black PN may be converted to the corresponding aluminium lake in which case only the requirements in the General Specifications for Aluminium Lakes of Colouring Matters apply.
Synonyms: INS No. 151, CI Food Black 1, CI (1975) No. 28440, Black PN, Brilliant Black BN Black PN; CI (1975) No. 28440; CI Food Black 1
Assay, identification and purity criteria
Description and assay
- Specification history
- Prepared at the 87 th JECFA and published in JECFA Monograph 23 (2019) superseding specifications prepared at the 28 th JECFA (1984), published in FNP 31/1 (1984) and in FNP 52 (1992). Metals and arsenic specifications revised at the 59 th JECFA (2002). An ADI of 0-1 mg/kg bw was established at the 25 th JECFA (1981) and confirmed at the 87 th JECFA (2019).
- Chemical name
- Tetrasodium 4-acetamido-5-hydroxy-6-[7-sulfonato-4-(4-sulfonato-phenylazo)-1-naphthylazo]-1,7-naphthalenedisulfonate Tetrasodium salt of 4-(acetylamino)-5-hydroxy-6-[[7-sulfo-4-[(4-sulfophenyl)azo]-1-naphthalenyl]azo]-1,7-naphthalenedisulfonic acid Tetrasodium;(6E)-4-acetamido-5-oxo-6-[[7-sulfonato-4-[(4-sulfonatophenyl)2pprox.2]naphthalen-1-yl]hydrazinylidene]naphthalene-1,7-disulfonate
- C.A.S. number
- 2519-30-4
- Chemical formula
- C 28 H 17 N 5 Na 4 O 14 S 4
- Formula weight
- 867.69
- Assay
- Not less than 80% total colouring matters
- DESCRIPTION
- Black powder or granules
- FUNCTIONAL USES
- Colour
- METHOD OF ASSAY
- Determine total colouring matters content by spectrophotometry using Procedure 1 in Volume 4 (under “Specific Methods, Food Colours”) and an appropriate solvent. Analyze immediately after preparation. Using water as the solvent: absorptivity (a) = 53.0 l/(g·cm) and wavelength of maximum absorbance = 572 nm.
Identification
- Solubility (Vol. 4)
- Soluble in water, sparingly soluble in ethanol.
- Spectrophotometry (Vol. 4)
- Maximum wavelength approximately 572 nm Determine the UV-visible absorption spectrum of the sample dissolved in water.
Purity criteria
- Loss on drying, chloride and sulfate as sodium salts (Vol. 4)
- Not more than 20% Determine chloride as sodium chloride, sulfate as sodium sulfate, and loss on drying (135°, 6 h) as described in Volume 4 (under “Specific Methods, Food Colours”).
- Water insoluble matter (Vol. 4)
- Not more than 0.2%
- Lead (Vol. 4)
- Not more than 2 mg/kg Determine using a method appropriate to the specified level. The selection of sample size and method of sample preparation may be based on the principles of the method described in Volume 4 (under “General Methods, Metallic Impurities”).
- Subsidiary colouring matters
- Not more than 4% See description under TESTS
- Organic compounds other than colouring matters
- Not more than 0.8% sum of 4-(acetylamino)-5-hydroxy-1,7-naphthalenedisulfonic acid, 4-amino-5-hydroxynaphthalene-1,7-disulfonic acid, 8-amino-2-naphthalenesulfonic acid, sulfanilic acid, and 4,4’-(diazoamino)dibenzenesulfonic acid See description under TESTS
- Unsulfonated primary aromatic amines (Vol. 4)
- Not more than 0.01% calculated as aniline
- Ether extractable matter (Vol. 4)
- Not more than 0.2%
- Test: Subsidiary colouring matters
- Determine subsidiary colouring matters content by reversed-phase HPLC (Vol. 4) using the following conditions: - Column: Atlantis T3 RP18 (4.6 mm x 150 mm, 3 μm particle size) or equivalent - Eluent A: 0.04 M ammonium acetate in water - Eluent B: methanol - Injection volume: 20 μl - Column temperature: 35 ° - Detector: UV-visible/diode array at 572 nm - Flow rate: 0.8 ml/min Gradient: Elution time Eluent A Eluent B (min) (%) (%) 0 98 2 15 60 40 30 60 40 35 10 90 35.1 98 2 45 98 2 Reagents: HPLC grade Standard: - Brilliant Black PN (C.A.S. No. 2519 -30-4 ) – USP Brilliant Black PN RS or equivalent Prepare standard solutions as required using 0.1 M ammonium acetate in water as the solvent. Sample solution (0.1 mg/ml): Weigh accurately 100±2 mg of sample into a 100 ml volumetric flask and dilute to volume with 0.1 M ammonium acetate in water. Dilute the solution, if required, to separate subsidiary colours from the primary colour component in order to improve their resolution. Procedure: Inject the standard and sample solutions. Integrate all peaks in the chromatogram of the sample solution. Identify the peak of Brilliant Black PN from the chromatogram of the standard solution. Determine the ratio of the sum of all peak areas not corresponding to Brilliant Black PN to the sum of all peak areas. Calculate the result for subsidiary colours as a percentage of the sample weight.
- Test: Organic compounds other than colouring matters
- Determine organic compounds other than colouring matters content by reversed-phase HPLC (Vol. 4) using the following conditions: - Column: Atlantis T3 RP18 (4.6 mm x 150 mm, 3 μm particle size) or equivalent - Eluent A: 0.04 M ammonium acetate in water - Eluent B: methanol - Injection volume: 20 μl - Column temperature: 35° - Detector: UV-visible/diode array at 254 nm - Flow rate: 0.8 ml/min Gradient: Elution time Eluent A Eluent B (min) (%) (%) 0 98 2 15 60 40 30 60 40 35 10 90 35.1 98 2 45 98 2 Reagents: HPLC grade Standards: - 4-(Acetylamino)-5-hydroxy-1,7-naphthalenedisulfonic acid (N-acetyl K acid) (C.A.S. 6409-21-8) – ChemTik, Cat. No. CTK2F3097 or equivalent - 4-Amino-5-hydroxynaphthalene-1,7-disulfonic acid (K acid) (C.A.S. 130-23-4) – BOC Sciences, Cat. No. 130-23-4 or equivalent - 8-Amino-2-naphthalenesulfonic acid (1,7-Cleve’s acid) (C.A.S. 119-28-8) – TCI Cat. No. A0356 or equivalent - Sulfanilic acid (4-aminobenzenesulfonic acid) (C.A.S. 121-57-3) – Sigma, Cat. No. 251917 or equivalent - 4,4’-(Diazoamino)dibenzenesulfonic acid (DAADBSA) (C.A.S. 17596-06-4) – Wako Cat. No. 040 33231 or equivalent Prepare standard solutions as required using the following solvents: - Dissolve N-acetyl K acid, K acid, and sulfanilic acid in water - Dissolve 1,7-Cleve’s acid in methanol/water (1:1) - Dissolve DAADBSA in water containing 1 drop of 50% sodium hydroxide in water Sample preparation: Weigh accurately 100±2 mg of sample into a 100 ml volumetric flask and dilute to volume with 0.1 M ammonium acetate in water. Procedure: Inject the standard solutions. Integrate the chromatogram peaks obtained for N-acetyl K acid, K acid, 1,7-Cleve’s acid, sulfanilic acid, and DAADBSA. Construct the relevant standard curves. Inject the sample solution and determine the concentration of each analyte from its respective standard curve.Calculate the percentage of each analyte in the sample and calculate their sum.
Every name it appears under
81 recorded names. A label may use any of them.
E number
- E151
INS number
- 151
CAS registry number
- 2519-30-4
As it appears in regulation
- Brilliant Black PN
Other names
- 1743 Black
- 2WPR32U0CP
- ACID BLACK 3 (NAPHTHOL BLACK C.I. 27260)
- AGKKBBSOKGLVTM-HZGWVLLFSA-J
- Black BN
- Black PN
- Black PN (~80%)
- Black PN (~80per cent)
- black-pn
- Blue Black BN
- Brillant Black 1
- Brilliant Acid Black BN Extra Pure A
- Brilliant Acid Black BNA Export
- Brilliant Black
- BRILLIANT BLACK (BLACK PN)
- Brilliant black 1
- Brilliant Black A
- Brilliant Black BN
- Brilliant Black N. FQ
- Brilliant Black NAF
- Brilliant Black PN
- BRILLIANTBLACKBN
- Brilliantschwarz BN
- C.I. FOOD BLACK 1
- C.I. Food Black 1, tetrasodium salt
- C.I. Food Black-1
- CCRIS 113
- CERN brilantni PN [Czech]
- CERN potravinarska 1 [Czech]
- Certicol Black PNW
- CI Food Black 1
- Cilefa Black B
- COLOUR INDEX NO. 28440
- E 151
- E151; Brilliant Black BN (E151)
- Edicol Supra Black BN
- Food black 1
- Hexacol Black PN
- INS NO.151
- INS-151
- L Black 8000
- L-Schwarz 1
- Melan Black
- Noir brillant BN
- XYLENE BLACK
- Xylene Black F
Systematic names
- 1,7-Naphthalenedisulfonic acid, 4-(acetylamino)-5-hydroxy-6-((7-sulfo-4-((4-sulfophenyl)azo)-1-naphthalenyl)azo)-, tetrasodium salt
- 1,7-Naphthalenedisulfonic acid, 4-acetamido-5-hydroxy-6-((7-sulfo-4-((p-sulfophenyl)azo)-1-naphthyl)azo)-, tetrasodium salt
- 2-(4-(p-Sulfophenylazo)-7-sulfo-1-naphthylazo)-8-acetamido-1-naphthol-3,5-di-sulonic acid, tetrasodium salt
- Sodium 4-acetamido-5-hydroxy-6-((7-sulfonato-4-((4-sulfonatophenyl)diazenyl)naphthalen-1-yl)diazenyl)naphthalene-1,7-disulfonate
- Tetrasodium 1-acetamido-2-hydroxy-3-(4-((4-sulphonatophenylazo)-7-sulphonato-1-naphthylazo))naphthalene-4,6-disulphonate
- tetrasodium 4-(acetylamino)-5-hydroxy-6-[(E)-{7-sulfonato-4-[(E)-(4-sulfonatophenyl)diazenyl]naphthalen-1-yl}diazenyl]naphthalene-1,7-disulfonate
- Tetrasodium;(6E)-4-acetamido-5-oxo-6-[[7-sulfonato-4-[(4-sulfonatophenyl)diazenyl]naphthalen-1-yl]hydrazinylidene]naphthalene-1,7-disulfonate
- tetrasodium;4-acetamido-5-hydroxy-6-[[7-sulfonato-4-[(4-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,7-disulfonate
The EU re-evaluation programme
Every additive authorised in the EU before 20 January 2009 was put back through EFSA by Commission Regulation (EU) No 257/2010, and this one is named in it. What the Regulation required is below; whether the opinion has since been published is not something this site records.
- To be evaluated by 15 April 2010. Named in Annex II, Part I, point 1 as “Brilliant Black BN, Black PN”, among the additives given priority within its class.
Hazard reference values
The two committees set different figures. EFSA's acceptable daily intake is 5 mg/kg bw/day; JECFA's is 1 mg/kg bw/day (2019). An acceptable daily intake is a reference value set by a committee, not a threshold above which harm begins. The lower figure is not a finding that the other body was wrong: the two work to different terms of reference, on their own timetables, and sometimes from different data. This site states both and chooses between them nowhere. See where the two committees differ.
| Type | Value | Population | Assessed by | Opinion |
|---|---|---|---|---|
| ADI | 1 mg/kg bw/day | — | JECFA | 2019 |
| ADI | 5 mg/kg bw/day | consumers | EFSA | not identified in the dataset |
Evidence and how bodies read it
What assessing bodies concluded
Each conclusion is paraphrased in the body's own framing, from the published opinion linked beneath it. Where bodies differ, both stand; this site does not adjudicate between them or add a view of its own.
EFSA 2015
In a refined exposure assessment for Brilliant Black BN (E 151), EFSA found that high-level exposure based on maximum permitted levels exceeded the ADI of 5 mg/kg bw/day for toddlers and children in some surveys, but that exposure was below the ADI for all population groups in the refined scenarios.
EFSA 2010
The ANS Panel concluded that the data gave no reason to revise the ADI of 5 mg/kg bw/day for Brilliant Black BN (E 151), noting negative long-term carcinogenicity studies despite some positive in vitro genotoxicity findings. Refined intake estimates were generally below the ADI, although the 95th percentile for children under 10 could exceed it at the upper end of the range.
Common questions
Assembled from what is above, in the words the questions are usually asked in. Each answer is the same statement the relevant section makes, with the same citations behind it.
- What is E 151?
- E 151 is Brilliant black (Black PN). Brilliant Black PN is a synthetic black dye used in sauces, preserved fish and confectionery, usually to deepen other colours rather than on its own.
- What is Brilliant black (Black PN) used for in food?
- It is listed as a colour — the role Codex and the EU assign it. This page shows every function each regulator records, with the citation for each.
- Where is Brilliant black (Black PN) permitted?
- Of the seven regulators this site reads, Australia and New Zealand, the EU, Great Britain and the Codex standard permit it. Each permission is for named foods at named levels, not a blanket one; the table on this page gives them with citations.
- Is Brilliant black (Black PN) vegan?
- Yes. Brilliant black (Black PN) is not derived from animals, and is suitable for vegetarians. This page says what it is made from and how.
Sources for this page
- anz retrieved 2026-10-17
- eu retrieved 2026-10-18
- gb retrieved 2026-10-18
- gsfa retrieved 2026-09-07
- euspecs retrieved 2026-10-18
- jecfaspecs retrieved 2026-09-23
Full licence terms and publisher details on Sources. How this page is built and updated: Method.
Machine-readable: a JSON record of this additive is given on request —how to ask for access.
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