Sodium dihydrogen citrate

INS 331(i)

Used as an acidity regulator — Codex also lists it as emulsifier, emulsifying, salt, sequestrant, stabilizer.

Monosodium citrate is an acidity regulator and sequestrant, used in drinks, jams and dairy products where a milder buffering effect than the trisodium salt is wanted.

Where it is and isn’t permitted

Status of Sodium dihydrogen citrate by jurisdiction. Every jurisdiction this site covers is listed, including those where the substance does not appear.
JurisdictionStatusScope and limitsCitation
United StatesFood and Drug AdministrationNot listedDoes not appear on this jurisdiction’s permitted list. That is not the same as being prohibited.
Codex AlimentariusCodex Alimentarius Commission / JECFAPermitted, with conditions

23 food categories

highest permitted level 5,000 mg/kg

Show every food category
  • 01.1.3 Fluid Buttermilk (plain) — GMP
  • 01.2.1.2 Fermented milks (plain), heat-treated after fermentation — GMP
  • 01.2.2 Renneted milk (plain) — GMP
  • 01.4.1 Pasteurized cream (plain) — GMP
  • 01.4.2 Sterilized and UHT creams, whipping and whipped creams, and reduced fat creams (plain) — GMP
  • 01.8.2 Dried whey and whey products, excluding whey cheeses — GMP
  • 02.1.1 Butter oil, anhydrous milkfat, ghee — GMP
  • 02.1.2 Vegetable oils and fats — GMP
  • 02.1.3 Lard, tallow, fish oil, and other animal fats — GMP
  • 04.2.1.1 Untreated fresh vegetables, (including mushrooms and fungi, roots and tubers, pulses and legumes (including soybeans), and aloe vera), seaweeds and nuts and seeds — GMP
  • 04.2.2.1 Frozen vegetables (including mushrooms and fungi, roots and tubers, pulses and legumes, and aloe vera), seaweeds and nuts and seeds — GMP
  • 08.1.1 Fresh meat, poultry and game, whole pieces or cuts — GMP
  • 08.1.2 Fresh meat, poultry and game, comminuted — GMP
  • 09.2 Processed fish and fish products, including molluscs, crustaceans, and echinoderms — GMP
  • 10.2.1 Liquid egg products — GMP
  • 10.2.2 Frozen egg products — GMP
  • 11.4 Other sugars and syrups (e.g. xylose, maple syrup, sugar toppings) — GMP
  • 12.1.2 Salt substitutes — GMP
  • 13.1.1 Infant formulae — GMP
  • 13.1.2 Follow-up formulae — GMP
  • 13.1.3 Formulae for special medical purposes for infants — GMP
  • 13.2 Complementary foods for infants and young children — 5,000 mg/kg
  • 14.1.5 Coffee, coffee substitutes, tea, herbal infusions, and other hot cereal and grain beverages, excluding cocoa — GMP
CXS 192-1995 Table Three, INS 331(i)and 23 further provisionsretrieved 2026-09-07

What it is made from

Made by partially neutralising fermentation-derived citric acid with sodium.

  • Vegan
  • Vegetarian
InChIKey
HWPKGOGLCKPRLZ-UHFFFAOYSA-M
PubChem
CID 23666341

Every name it appears under

20 recorded names. A label may use any of them.

E number

  • E331I

INS number

  • 331(i)

CAS registry number

  • 18996-35-5

Other names

  • 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, monosodium salt
  • 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, sodium salt (1:1)
  • C6H7NaO7
  • Citric acid monosodium salt
  • mono sodium citrate
  • Monosodium citrate
  • Monosodium Citrate Anhydrous
  • sodium 3,4-dicarboxy-3-hydroxybutanoate
  • Sodium citrate monobasic
  • Sodium citrate monobasic, BioXtra, anhydrous, >=99.5% (T)
  • Sodium citrate monobasic, purum p.a., anhydrous, >=99.0% (T)
  • SODIUM DIHYDROGEN CITRATE
  • Sodium dihydrogencitrate
  • Sodium dihydrogencitrate, 99%
  • sodium,2-(carboxymethyl)-2,4-dihydroxy-4-oxobutanoate
  • sodium;2-(2-hydroxy-2-oxoethyl)-2,4-bis(oxidanyl)-4-oxidanylidene-butanoate
  • sodium;3-carboxy-3,5-dihydroxy-5-oxopentanoate

Hazard reference values

No reference value for this substance in the sources we hold.

Evidence and how bodies read it

Studies, and the differing conclusions regulators drew from them, are curated by hand rather than machine-read, and none has been written for this substance yet.

Sources for this page

  • gsfa retrieved 2026-09-07

Full licence terms and publisher details on Sources. How this page is built and updated: Method.

Machine-readable:/api/v1/additives/sodium-dihydrogen-citrate.json