Sorbitan tristearate
26658-19-5 · 86595-70-2 · 1,4-Anhydro-3,5,6-tri-O-octadecanoyl-D-glucitol · Anhydrosorbitol tristearate · E 492 · FCM no 651 · IJCWFDPJFXGQBN-RYNSOKOISA-N · INS NO.492 · INS-492 · Sorbitan tristearate · Sorbitan, trioctadecanoate · Span 65 · Tristearate de sorbitan · E492 · 492 · [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate · [(2R,3S,4R)-2-[1,2-di(octadecanoyloxy)ethyl]-4-hydroxyoxolan-3-yl] octadecanoate · Sorbitan tristearate · Sorbitaanitristearaatti · Sorbitaantristearaat · Sorbitan tristearat · Sorbitan tristearate · Sorbitano tristearatas · Sorbitantristearát · Sorbitāna tristearāts · Szorbitan-trisztearát · Triestearato de sorbitano · Tristearat de sorbitan · Tristearat tas-sorbitan · Tristearato di sorbitano · Tristearynian sorbitolu · TRISTÉARATE DE SORBITAN · Tristéarate de sorbitane · ΤΡΙΣΤΕΑΤΙΚΗ ΣΟΡΒΙΤΑΝΗ · Τριστεαρική σορβιτάνη · Сорбитан тристеаратE number E492INS 492CAS 26658-19-5
Listed as an emulsifier and a stabiliser by Canada and Codex.
Listed as emulsifiers (CA, Codex) · stabilisers (CA, Codex) · thickeners (CA)
- Canada: Emulsifying agent — Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)
- Canada: Emulsifying, stabilizing or thickening agent — Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)
- Codex Alimentarius: Emulsifier — CXS 192-1995 Table One, INS 492
- Canada: Emulsifying, stabilizing or thickening agent — Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)
- Codex Alimentarius: Stabilizer — CXS 192-1995 Table One, INS 492
- Canada: Emulsifying, stabilizing or thickening agent — Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)

Sorbitan tristearate is used chiefly in chocolate and confectionery coatings, where it slows the fat bloom that turns chocolate grey.
Where it is and isn’t permitted
| Jurisdiction | Status | Scope and limits | Citation |
|---|---|---|---|
| Australia and New Zealand | Permitted, with conditions | 54 food categories no numerical limit (good manufacturing practice) Show every food category
| Food Standards Code, Schedule 15, S15—5and 53 further provisionsretrieved 2026-10-17 |
| Canada | Permitted, with conditions | highest permitted level 350 % 5 permitted uses Show every permitted use
| Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)and 4 further provisionsretrieved 2026-10-17 |
| European Union | Permitted, with conditions | 20 food categories highest permitted level 10,000 mg/l Show every food category
| Regulation (EC) No 1333/2008, Annex IIand 19 further provisionsretrieved 2026-10-18 |
| Great Britain | Permitted, with conditions | 19 food categories highest permitted level 10,000 mg/kg or mg/l Show every food category
| Assimilated Regulation (EC) No 1333/2008and 18 further provisionsretrieved 2026-10-18 |
| Japan | No listing matchedThis site imports only Japan’s list of designated additives (Appended Table 1 to the Regulations for Enforcement of the Food Sanitation Act), matched by English name. Existing additives, natural flavouring agents and ordinary foods used as additives are permitted outside that list and are not imported, so an empty row does not show that Japan does not permit the substance. | ||
| South Korea | No listing matchedThis site imports Part III of South Korea’s Standards and Specifications for Food Additives, matched by CAS number, then INS number, then exact name. Mixed preparations and sanitisers are not imported, and an entry whose identifiers disagreed with a page’s is held for review, so an empty row does not show that South Korea does not permit the substance. | ||
| United States | Not listedDoes not appear on this jurisdiction’s permitted list. That is not the same as being prohibited. | ||
| Codex Alimentarius | Permitted, with conditions | 53 food categories highest permitted level 20,000 mg/kg Show every food category and its notes
| CXS 192-1995 Table One, INS 492and 52 further provisionsretrieved 2026-09-07 |
How much is permitted
A listing usually limits the quantity as well as the food. Only one of the forms that takes is a figure: quantum satis and good manufacturing practice permit the amount the technological effect requires and no more, which is a limit rather than the absence of one. Figures below are the range across every food category this page is listed in, and categories differ between regulators — see how much is permitted.
| Australia and New Zealand | — | 54 GMP |
|---|---|---|
| Canada | 350 mg/kg – 10,000 mg/kg | 3 numeric limit, 2 no quantity stated |
| European Union | 500 mg/kg – 10,000 mg/kg | 17 numeric limit, 3 quantum satis |
| Great Britain | 500 mg/kg – 10,000 mg/kg | 16 numeric limit, 3 quantum satis |
| Codex Alimentarius | 50 mg/kg – 20,000 mg/kg | 53 numeric limit |
What it is made from
Made by esterifying sorbitol with three stearic acid chains. The stearic acid may be of plant or animal origin.
- Vegan status depends on the source
- Vegetarian status depends on the source
- May raise a halal question
- May raise a kosher question
This is not an omission. What this additive is made from is not fixed — depending on the manufacturer it may be plant, animal or microbial in origin, nobody is required to say which, and the same product can change source between production runs. Ask the manufacturer if it matters to you; a label cannot answer it.
Compare other additives on the dietary indexes.
- CAS registry number
- 26658-19-5
- InChIKey
- IJCWFDPJFXGQBN-RYNSOKOISA-N
- PubChem
- CID 15181202
The two specifications, compared
The European Union sets identity and purity by regulation; JECFA publishes its own through FAO, advisory until a country adopts it. Both documents are below in full. These are the parameters each puts a number on.
| Parameter | European Union | JECFA |
|---|---|---|
| Assay | no less than 95 % | no less than 95 % |
| Sulphated ash | no more than 0.5 % | no more than 0.5 % |
| Lead | no more than 2 mg/kg | no more than 2 mg/kg |
| Arsenic | no more than 3 mg/kg | — |
| Mercury | no more than 1 mg/kg | — |
| Cadmium | no more than 1 mg/kg | — |
The two documents state the same figures for every parameter compared here.
How the EU defines it
The legal specification an additive must meet to be sold as this E number in the EU — what it is, how it may be made, and the purity it must reach. From Commission Regulation (EU) No 231/2012.
E 492 Sorbitan tristearate
A mixture of the partial esters of sorbitol and its anhydrides with edible, commercial stearic acid
Assay, identification and purity criteria
Description and assay
- Einecs
- 247-891-4
- Assay
- Content not less than 95 % of a mixture of sorbitol, sorbitan, and isosorbide esters
- Description
- Light, cream- to tan-coloured beads or flakes or hard, waxy solid with a slight odour
Identification
- Solubility
- Slightly soluble in toluene, ether, carbon tetrachloride and ethyl acetate; dispersible in petroleum ether, mineral oil, vegetable oils, acetone and dioxane; insoluble in water, methanol and ethanol
- Identification test
- By acid value, iodine value (not more than 4), gas chromatography
- Infrared absorption spectrum
- Characteristic of a partial fatty acid ester of a polyol
Purity criteria
- Water content
- Not more than 2 % (Karl Fischer method)
- Sulphated ash
- Not more than 0,5 %
- Acid value
- Not more than 15
- Saponification value
- Not less than 176 and not more than 188
- Hydroxyl value
- Not less than 66 and not more than 80
- Arsenic
- Not more than 3 mg/kg
- Lead
- Not more than 2 mg/kg
- Mercury
- Not more than 1 mg/kg
- Cadmium
- Not more than 1 mg/kg
How JECFA defines it
The international specification for identity and purity, prepared by the Joint FAO/WHO Expert Committee on Food Additives and published by FAO. It is a different document from any above, written by a different body and revised on its own cycle; it is advisory, and a country adopts it or does not.
INS 492 Sorbitan Tristearate
A mixture of the partial esters of sorbitol and its mono- and dianhydrides with edible stearic acid
Synonyms: INS No. 492
Assay, identification and purity criteria
Description and assay
- Specification history
- Prepared at the 39th JECFA (1992), published in FNP 52 Add 1 (1992) superseding specifications prepared at the 17th JECFA, published in FNP 4 (1978). Metals and arsenic specifications revised at the 55th JECFA (2000). A group ADI of 0-25 mg/kg bw as the sum of sorbitan esters of lauric, oleic, palmitic and stearic acids was established at the 26th JECFA (1982
- C.A.S. number
- 26658-19-5
- Structural formula
- Contains stearic acid esterified with polyols derived from sorbitol, including the following types:
- Assay
- Saponification of 100 g of the product shall yield not less than 14 g and not more than 21 g of polyols and not less than 85 g and not more than 92 g of fatty acids; and the polyol content shall be not less than 95% of a mixture of sorbitol, 1,4- sorbitan and isosorbide.
- DESCRIPTION
- Light cream- to tan beads or flakes or hard, waxy solid
- FUNCTIONAL USES
- Emulsifier
- METHOD OF ASSAY
- Transfer about 25 g of the sample, accurately weighed, into a 500-ml round-bottom flask, add 250 ml of alcohol and 7.5 g of potassium hydroxide, and mix. Connect a suitable condenser to the flask, reflux the mixture for 1 to 2 h, and then transfer to an 800-ml beaker, rinsing the flask with about 100 ml of water and adding it to the beaker. Heat on a steam bath to evaporate the alcohol, adding water occasionally to replace the alcohol, and evaporate until the odour of alcohol can no longer be detected. Adjust the final volume to about 250 ml with hot water. Neutralize the soap solution with dilute sulfuric acid (1 in 2), add 10% in excess, and heat, while stirring, until the fatty acid layer separates. Transfer the fatty acids to a 500-ml separator, wash with three or four 20-ml portions of hot water to remove polyols, and combine the washings with the original aqueous polyol layer from the saponification. Extract the combined aqueous layer with three 20-ml portions of petroleum ether, add the extracts to the fatty acid layer, evaporate to dryness in a tared dish, cool and weigh. Neutralize the polyol solution with a 1 in 10 solution of potassium hydroxide to pH 7 using a suitable pH meter. Evaporate this solution to a moist residue, and separate the polyols from the salts by several extractions with hot alcohol. Evaporate the alcohol extracts on a steam bath to dryness in a tared dish, cool, and weigh. Avoid excessive drying and heating. Assay another 25 g sample by the Sorbitan Ester Content procedure to determine percent sorbitan ester.
Identification
- Solubility (Vol. 4)
- Slightly soluble in toluene, ether, carbon tetrachloride and ethyl acetate; dispersible in petroleum ether, mineral oil, vegetable oils, acetone and dioxane; insoluble in water, methanol and ethanol.
- Congealing range (Vol. 4)
- 47 o - 50 o
Purity criteria
- Water (Vol. 4)
- Not more than 1.5% (Karl Fischer Method)
- Sulfated ash (Vol. 4)
- Not more than 0.5%
- Acid value (Vol. 4)
- Not more than 15
- Saponification value (Vol. 4)
- Not less than 176 and not more than 188
- Hydroxyl value (Vol. 4)
- Not less than 66 and not more than 80
- Lead (Vol. 4)
- Not more than 2 mg/kg Determine using an atomic absorption technique appropriate to the specified level. The selection of sample size and method of sample preparation may be based on the principles of the method described in Volume 4, “Instrumental Methods.”
Authorised in other additives, enzymes, flavourings and nutrients
These authorisations are not for use in food. They let this substance be used inside another additive, a food enzyme, a flavouring or a nutrient preparation — often as a carrier — and it reaches food only as part of that product. Annex III to Regulation (EC) No 1333/2008.
| Part | May be used in | Maximum level | Citation |
|---|---|---|---|
| Annex III, Part 1: Carriers in food additives | Colours and antifoaming agentsAuthorised as a member of Table 5 of Part 6 (Sorbitan esters), listed as "E 491 – E 495 Sorbitan esters (Table 5 of Part 6)" | quantum satis | Regulation (EC) No 1333/2008, Annex III, Part 1, via Table 5 of Part 6 |
| Annex III, Part 1: Carriers in food additives | Glazing agents for fruitAuthorised as a member of Table 5 of Part 6 (Sorbitan esters), listed as "E 491 – E 495 Sorbitan esters" | quantum satis | Regulation (EC) No 1333/2008, Annex III, Part 1, via Table 5 of Part 6 |
| Annex III, Part 2: Food additives other than carriers in food additives | Preparations of colours, anti-foaming agents and glazing agents for fruitAuthorised as a member of Table 5 of Part 6 (Sorbitan esters), listed as "E 491 – E 495 Sorbitan esters (Table 5 of Part 6)" Note (1): Except enzymes authorised as food additives. | quantum satis | Regulation (EC) No 1333/2008, Annex III, Part 2, via Table 5 of Part 6 |
| Annex III, Part 5, Section A: Food additives added in nutrients except in nutrients intended to be used in foodstuffs listed in Part E, point 01.10, of Annex II and foodstuffs for infants and young children listed in Part E, point 13.1, of Annex II | In beta carotene, lutein, lycopene and vitamin E preparationsAuthorised as a member of Table 5 of Part 6 (Sorbitan esters), listed as "E 491 – E 495 Sorbitan esters (Table 5 of Part 6)" Can be used as a carrier: Yes | quantum satis | Regulation (EC) No 1333/2008, Annex III, Part 5, Section A, via Table 5 of Part 6 |
| Annex III, Part 5, Section A: Food additives added in nutrients except in nutrients intended to be used in foodstuffs listed in Part E, point 01.10, of Annex II and foodstuffs for infants and young children listed in Part E, point 13.1, of Annex II | In vitamin A and D preparationsAuthorised as a member of Table 5 of Part 6 (Sorbitan esters), listed as "E 491 – E 495 Sorbitan esters (Table 5 of Part 6)" Can be used as a carrier: Yes | 2 mg/kg in final food | Regulation (EC) No 1333/2008, Annex III, Part 5, Section A, via Table 5 of Part 6 |
Every name it appears under
36 recorded names. A label may use any of them.
E number
- E492
INS number
- 492
CAS registry number
- 26658-19-5
- 86595-70-2
As it appears in regulation
- Sorbitan tristearate
Other names
- 1,4-Anhydro-3,5,6-tri-O-octadecanoyl-D-glucitol
- Anhydrosorbitol tristearate
- E 492
- FCM no 651
- IJCWFDPJFXGQBN-RYNSOKOISA-N
- INS NO.492
- INS-492
- Sorbitan tristearate
- Sorbitan, trioctadecanoate
- Span 65
- Tristearate de sorbitan
Systematic names
- [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate
- [(2R,3S,4R)-2-[1,2-di(octadecanoyloxy)ethyl]-4-hydroxyoxolan-3-yl] octadecanoate
Hazard reference values
| Type | Value | Population | Assessed by | Opinion |
|---|---|---|---|---|
| ADI | 10 mg/kg bw/day | consumers | EFSA ANS | 2017 |
Evidence and how bodies read it
What assessing bodies concluded
Each conclusion is paraphrased in the body's own framing, from the published opinion linked beneath it. Where bodies differ, both stand; this site does not adjudicate between them or add a view of its own.
EFSA 2017
The ANS Panel found no genotoxicity concern for the sorbitan esters (E 491–E 495) and derived a single group ADI of 10 mg/kg bw/day expressed as sorbitan (equivalent to 26 mg sorbitan monostearate/kg bw/day), replacing two separate SCF group ADIs. Exposure did not exceed this ADI in any population group.
Common questions
Assembled from what is above, in the words the questions are usually asked in. Each answer is the same statement the relevant section makes, with the same citations behind it.
- What is E 492?
- E 492 is Sorbitan tristearate. Sorbitan tristearate is used chiefly in chocolate and confectionery coatings, where it slows the fat bloom that turns chocolate grey.
- What is Sorbitan tristearate used for in food?
- It is listed as an emulsifier and a stabiliser — the role Canada and Codex assign it. This page shows every function each regulator records, with the citation for each.
- Where is Sorbitan tristearate permitted?
- Of the seven regulators this site reads, Australia and New Zealand, Canada, the EU, Great Britain and the Codex standard permit it. Each permission is for named foods at named levels, not a blanket one; the table on this page gives them with citations.
- Is Sorbitan tristearate vegan?
- It depends on the source, and a label will not tell you. Sorbitan tristearate can be made from plant or animal material, manufacturers are not obliged to say which, and the same product can change between production runs. Anyone who needs to know has to ask the manufacturer.
Sources for this page
- anz retrieved 2026-10-17
- ca retrieved 2026-10-17
- eu retrieved 2026-10-18
- gb retrieved 2026-10-18
- gsfa retrieved 2026-09-07
- euspecs retrieved 2026-10-18
- jecfaspecs retrieved 2026-09-23
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