Propylene glycol alginate
9005-37-2 · E 405 · Propane-1, 2-diol alginate · PROPYLENE GLYCOL ALGINATE · E405 · 405 · Propane-1, 2-diol alginate · Propylene glycol alginate · 1,2-PROPAANDIOOLALGINAAT · 1,2-propandiolio alginatas · 1,2-Propylenglykolalginat · 1,2-Propándiolalginát · ALGINAT DE 1,2-PROPANDIOL · Alginat de propan-1, 2-diol · Alginate de propane-1,2-diol · Alginato de propano-1,2-diol · Alginato de propilenoglicol (alginato de propano-1,2-diol) · Alginato di propan-1,2-diolo · Alginian glikolu propylenowego · ALĠINAT TAL-PROPAN-1,2-DIOL · Propaan-1,2-dioolalginaat · Propan-1,2-diol alginat · Propan-1,2-diol-alginát · Propane-1, 2-diol alginate · Propyleenglycolalginaat · Propyleeniglykolialginaatti · PROPYLENGLYCOL-ALGINAT · Propylenglycolalginat · Propān-1,2-diola algināts · Αλγινική προπανοδιόλη-1,2 · Пропан-1,2-диол алгинатE number E405INS 405CAS 9005-37-2
Listed as an emulsifier, a thickener and a stabiliser by Canada, Codex and the US.
Listed as emulsifiers (CA, US, Codex) · thickeners (CA, US, Codex) · stabilisers (CA, US, Codex) · gelling agents (Codex) · flavour enhancers (US) · glazing and surface-finishing agents (US) · bulking agents (Codex) · foaming and whipping agents (Codex) · flavouring agents and adjuvants (US) · carriers (Codex) · formulation aids (US) · surface-active agents (US) · solvents and vehicles (US) · processing aids (US)
- Canada: Emulsifying agent — Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)
- Canada: Emulsifying, stabilizing or thickening agent — Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)
- United States: Emulsifier or emulsifier salt — FDA, Substances Added to Food: PROPYLENE GLYCOL ALGINATE
- Codex Alimentarius: Emulsifier — CXS 192-1995 Table One, INS 405
- Canada: Emulsifying, stabilizing or thickening agent — Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)
- Canada: Thickening agent — Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)
- United States: Stabilizer or thickener — FDA, Substances Added to Food: PROPYLENE GLYCOL ALGINATE
- Codex Alimentarius: Thickener — CXS 192-1995 Table One, INS 405
- Canada: Emulsifying, stabilizing or thickening agent — Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)
- Canada: Stabilizing agent — Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)
- United States: Stabilizer or thickener — FDA, Substances Added to Food: PROPYLENE GLYCOL ALGINATE
- Codex Alimentarius: Stabilizer — CXS 192-1995 Table One, INS 405
- Codex Alimentarius: Gelling agent — CXS 192-1995 Table One, INS 405
- United States: Flavor enhancer — FDA, Substances Added to Food: PROPYLENE GLYCOL ALGINATE
- United States: Surface-finishing agent — FDA, Substances Added to Food: PROPYLENE GLYCOL ALGINATE
- Codex Alimentarius: Bulking agent — CXS 192-1995 Table One, INS 405
- Codex Alimentarius: Foaming agent — CXS 192-1995 Table One, INS 405
- United States: Flavoring agent or adjuvant — FDA, Substances Added to Food: PROPYLENE GLYCOL ALGINATE
- Codex Alimentarius: Carrier — CXS 192-1995 Table One, INS 405
- United States: Formulation aid — FDA, Substances Added to Food: PROPYLENE GLYCOL ALGINATE
- United States: Surface-active agent — FDA, Substances Added to Food: PROPYLENE GLYCOL ALGINATE
- United States: Solvent or vehicle — FDA, Substances Added to Food: PROPYLENE GLYCOL ALGINATE
- United States: Processing aid — FDA, Substances Added to Food: PROPYLENE GLYCOL ALGINATE
Propylene glycol alginate is an alginate modified to survive acid, which makes it the thickener of choice for salad dressings and for stabilising beer foam.
Where it is and isn’t permitted
| Jurisdiction | Status | Scope and limits | Citation |
|---|---|---|---|
| Australia and New Zealand | Permitted, with conditions | 55 food categories no numerical limit (good manufacturing practice) Show every food category
| Food Standards Code, Schedule 15, S15—5and 54 further provisionsretrieved 2026-10-17 |
| Canada | Permitted, with conditions | no numerical limit (good manufacturing practice) 15 permitted uses Show every permitted use
| Health Canada, List of Permitted Emulsifying, Gelling, Stabilizing or Thickening Agents (List 4)and 14 further provisionsretrieved 2026-10-17 |
| European Union | Permitted, with conditions | 21 food categories highest permitted level 10,000 mg/kg Show every food category
| Regulation (EC) No 1333/2008and 20 further provisionsretrieved 2026-10-18 |
| Great Britain | Permitted, with conditions | 20 food categories highest permitted level 10,000 mg/kg or mg/l Show every food category
| Assimilated Regulation (EC) No 1333/2008and 19 further provisionsretrieved 2026-10-18 |
| Japan | Permitted, with conditions | Designated additive: Appended Table 1, item 40, アルギン酸プロピレングリコールエステル (“Propylene Glycol Alginate” in the unofficial English translation). …Designated additive: Appended Table 1, item 40, アルギン酸プロピレングリコールエステル (“Propylene Glycol Alginate” in the unofficial English translation). Standards for use — Specifications and Standards for Foods, Food Additives, etc. (MHW Notification No. 370 of 1959), Part II (Food Additives), F (Standards for use), entry アルギン酸プロピレングリコールエステル: (1) [sets maximum levels of use for the foods stated] “アルギン酸プロピレングリコールエステルの使用量は、アルギン酸プロピレングリコールエステルとして、食品の1.0%以下でなければならない。” The Japanese is the standard as published. There is no official English translation of the Notification; the English in square brackets is this site’s description of what each sentence does, not a translation of the foods or the levels. Compositional specifications for this additive, in the same Notification, are not imported and are not shown here; nor are the general rules in F 添加物一般, which apply to every additive. | Regulations for Enforcement of the Food Sanitation Act (MHW Ordinance No. 23 of 1948), Appended Table 1retrieved 2026-10-18 |
| South Korea | Permitted, with conditions | Designated food additive: Standards and Specifications for Food Additives, Part III, 1. …Designated food additive: Standards and Specifications for Food Additives, Part III, 1. 일반식품첨가물 (general food additives), 알긴산프로필렌글리콜 (“Propylene Glycol Alginate”, the English the Code prints beside it). Main use (주용도) of 알긴산프로필렌글리콜: 유화제, 증점제, 안정제. Standard for use (사용기준) of 알긴산프로필렌글리콜: (1) [sets a limit on the amount used] “알긴산프로필렌글리콜의 사용량은 알긴산프로필렌글리콜로서 식품의 1% 이하이어야 한다.” The Korean is the standard as published. There is no official English translation of the current Code (the English version on MFDS’s website is the 2020 edition and has no legal effect); the English in square brackets is this site’s description of what each sentence does, not a translation of the foods or the levels. Compositional specifications (Part IV) are not imported, nor are the general standards in Part II, which apply to every additive. | Standards and Specifications for Food Additives (식품첨가물의 기준 및 규격), MFDS Notification, Part III (Standards for use, by item)retrieved 2026-10-18 |
| United States | Permitted, with conditions | 21 CFR 172.858retrieved 2026-10-17 | |
| Codex Alimentarius | Permitted, with conditions | 55 food categories highest permitted level 20,000 mg/kg Show every food category and its notes
| CXS 192-1995 Table One, INS 405and 54 further provisionsretrieved 2026-09-07 |
How much is permitted
A listing usually limits the quantity as well as the food. Only one of the forms that takes is a figure: quantum satis and good manufacturing practice permit the amount the technological effect requires and no more, which is a limit rather than the absence of one. Figures below are the range across every food category this page is listed in, and categories differ between regulators — see how much is permitted.
| Australia and New Zealand | — | 55 GMP |
|---|---|---|
| Canada | — | 4 GMP, 11 no quantity stated |
| European Union | 100 mg/kg – 10,000 mg/kg | 21 numeric limit |
| Great Britain | 100 mg/kg – 10,000 mg/kg | 19 numeric limit, 1 several limits |
| Japan | — | 1 no quantity stated |
| South Korea | — | 1 no quantity stated |
| United States | — | 1 no quantity stated |
| Codex Alimentarius | 500 mg/kg – 20,000 mg/kg | 55 numeric limit |
What it is made from
Made by reacting seaweed alginate with propylene oxide. The alginate is of plant origin; the propylene oxide is petroleum-derived.
- Vegan
- Vegetarian
Compare other additives on the dietary indexes.
- CAS registry number
- 9005-37-2
The two specifications, compared
The European Union sets identity and purity by regulation; JECFA publishes its own through FAO, advisory until a country adopts it. Both documents are below in full. These are the parameters each puts a number on.
| Parameter | European Union | JECFA |
|---|---|---|
| Assay | no less than 16 % | no less than 16 % |
| Loss on drying | no more than 20 % | no more than 20 % |
| Lead | no more than 5 mg/kg | no more than 5 mg/kg |
| Arsenic | no more than 3 mg/kg | no more than 3 mg/kg |
| Mercury | no more than 1 mg/kg | — |
| Cadmium | no more than 1 mg/kg | — |
The two documents state the same figures for every parameter compared here.
How the EU defines it
The legal specification an additive must meet to be sold as this E number in the EU — what it is, how it may be made, and the purity it must reach. From Commission Regulation (EU) No 231/2012.
E 405 Propane-1,2-diol alginate
Synonyms: Hydroxypropyl alginate; 1,2-Propanediol ester of alginic acid; Propylene glycol alginate
Assay, identification and purity criteria
Description and assay
- Chemical name
- 1,2-Propanediol ester of alginic acid; varies in composition according to its degree of esterification and the percentage of free and neutralised carboxyl groups in the molecule
- Chemical formula
- (C₉H₁₄O₇)ₙ (esterified)
- Molecular weight
- 10 000 -600 000 (typical average)
- Assay
- Yields, on the anhydrous basis, not less than 16 % and not more than 20 % of carbon dioxide (CO₂₎
- Description
- Nearly odourless, white to yellowish brown fibrous or granular powder
Identification
- Test for 1,2-propanediol
- Passes test (after hydrolysis)
- Test for alginic acid
- Passes test (after hydrolysis)
Purity criteria
- Loss on drying
- Not more than 20 % (105 °C, 4 hours)
- Total propane-1,2-diol content
- Not less than 15 % and not more than 45 %
- Free propane-1,2-diol content
- Not more than 15 %
- Water insoluble matter
- Not more than 2 % on the anhydrous basis
- Formaldehyde
- Not more than 50 mg/kg
- Arsenic
- Not more than 3 mg/kg
- Lead
- Not more than 5 mg/kg
- Mercury
- Not more than 1 mg/kg
- Cadmium
- Not more than 1 mg/kg
- Microbiological criteria: Total plate count
- Not more than 5 000 colonies per gram
- Microbiological criteria: Yeast and moulds
- Not more than 500 colonies per gram
- Microbiological criteria: Escherichia coli
- Absent in 5 g
- Microbiological criteria: Salmonella spp.
- Absent in 10 g
How JECFA defines it
The international specification for identity and purity, prepared by the Joint FAO/WHO Expert Committee on Food Additives and published by FAO. It is a different document from any above, written by a different body and revised on its own cycle; it is advisory, and a country adopts it or does not.
INS 405 Propylene Glycol Alginate
Propylene glycol alginate is an ester of alginic acid in which some of the carboxyl groups are esterified with propylene glycol, some neutralized with an appropriate alkali and some remain free.
Synonyms: 1,2-propane-diol ester of alginic acid; hydroxypropyl alginate; propane 1,2-diol alginate; INS No. 405.
Assay, identification and purity criteria
Description and assay
- Specification history
- Prepared at the 49th JECFA (1997), published in FNP 52 (1997) superseding specifications prepared at the 44th JECFA (1995), published in FNP 52 Add 3 (1995). An ADI of 0-70 mg/kg bw was established at the 41st JECFA (1993)
- C.A.S. number
- 9005-37-2
- Chemical formula
- (C 9 H 14 O 7 ) n (esterified)
- Formula weight
- Structural unit : 234.21 (theoretical) Macromolecule : 10,000 - 600,000 (typical average)
- Assay
- Yields, on the dried basis, not less than 16% and not more than 20% of carbon dioxide (CO 2 ).
- DESCRIPTION
- White to yellowish brown filamentous, grainy, granular or powdered forms
- FUNCTIONAL USES
- Stabilizer, thickener, emulsifier
- METHOD OF ASSAY
- Proceed as directed under Carbon Dioxide Determination by Decarboxylation in the General Methods (see Volume 4). Each ml of 0.25 N Sodium hydroxide consumed is equivalent to 5.5 mg of carbon dioxide (CO 2 ).
Identification
- Solubility (Vol. 4)
- Soluble in water giving a viscous, colloidal solution; soluble in up to 60% aqueous ethanol depending upon degree of esterification.
- Precipitate formation with sulphuric acid
- To 10 ml of a 1% solution of the sample add 1 ml of sodium hydroxide TS. Heat in a boiling water bath for about 5 min, cool and add 1 ml of dilute sulphuric acid TS. A gelatinous precipitate is formed.
- Precipitate formation with lead acetate
- To 5 ml of a 1% solution of the sample add 1 ml of lead acetate TS. A gelatinous precipitate is formed
Purity criteria
- Loss on drying (Vol. 4)
- Not more than 20% (105 o , 4 h)
- Water-insoluble matter
- Not more than 2% on the dried basis See description under TESTS
- Total propylene glycol
- Not less than 15% and not more than 45%. See description under TESTS.
- Free propylene glycol
- Not more than 15% See description under TESTS
- Arsenic (Vol. 4)
- Not more than 3 mg/kg (Method II)
- Lead (Vol. 4)
- Not more than 5 mg/kg Determine using an atomic absorption technique appropriate to the specified level. The selection of sample size and method of sample preparation may be based on the principles of the method described in Volume 4, “Instrumental Methods.”
- Microbiological criteria (Vol. 4)
- Total plate count: Not more than 5,000 colonies per gram. Initially prepare a 10 -1 dilution by adding a 50 g sample to 450 ml of Butterfield’s phosphate buffered dilution water and homogenizing in a high speed blender. Yeasts and moulds: Not more than 500 colonies per gram Coliforms: Negative by test Salmonella: Negative by test
- Test: Water-insoluble matter
- Disperse 2 g of the sample, weighed to the nearest 0.1 mg, in 800 ml of water in a 2,000-ml flask. Neutralize to pH 7 with sodium hydroxide TS and then add 3 ml in excess. Add 40 ml of hydrogen peroxide solution containing 30% by weight H 2 O 2 , cover the flask and boil for 1 h with frequent stirring. Filter while hot through a tared Gooch crucible provided with a glass fibre filter (2.4 cm, No 934 AH, Reeve Angel & Co, Clifton, N.Y., USA, or equivalent). If slow filtration is caused by high viscosity of the sample solution, boil until the viscosity is reduced enough to permit filtration. Wash the crucible thoroughly with hot water, dry the crucible and its contents at 105 o for 1 h, cool and weigh. Calculate as percentage of the dry weight.
- Test: Total propylene glycol
- Sample solution: Weigh, to the nearest 0.1 mg, 1 g of the sample previously dried and dissolve in 100 ml distilled water in a 400-ml beaker. After dissolution add 50 ml of 0.1 N sodium hydroxide and stir for 30 min. At the end of this period neutralize with 0.1 N hydrochloric acid and precipitate the gum with 25 ml of a 5% calcium chloride solution. Filter the mixture using fast filter paper collecting the filtrate in a 250-ml volumetric flask. Wash the precipitate with several small portions of distilled water combining the washings with the filtrate and dilute to the mark with distilled water. Periodic acid, 0.029 M: Add 5.500 g of periodic acid and 200 ml of distilled water to a 1-litre volumetric flask. Dilute to the mark with glacial acetic acid. Procedure: Pipette a 25-ml aliquot of the sample solution and 25 ml of the 0.029 M periodic acid into a 250-ml conical flask, swirl and let stand for 30 min. At the end of this period add approximately 2 g of potassium iodide and titrate with 0.1 N sodium thiosulfate using 1% starch solution as an indicator. Perform a blank determination using 50 ml of distilled water and 25 ml of 0.029 M periodic acid. Calculate the percentage of propylene glycol by the formula: where A = ml 0.1 N sodium thiosulfate used for blank B = ml 0.1 N sodium thiosulfate used for sample W = weight of the sample (in grams)
- Test: Free propylene glycol
- Determine the percentage of free propylene glycol in the sample by extracting 2 g of sample for 2 hours under reflux, using 80 ml of propan-2-ol. Allow the solution to cool to room temperature, then determine the quantity of free propylene glycol using titration with 0.029 M periodic acid as described under the procedure for Total propylene glycol.
Authorised in other additives, enzymes, flavourings and nutrients
These authorisations are not for use in food. They let this substance be used inside another additive, a food enzyme, a flavouring or a nutrient preparation — often as a carrier — and it reaches food only as part of that product. Annex III to Regulation (EC) No 1333/2008.
| Part | May be used in | Maximum level | Citation |
|---|---|---|---|
| Annex III, Part 1: Carriers in food additives | All food additives | quantum satis | Regulation (EC) No 1333/2008, Annex III, Part 1 |
Every name it appears under
31 recorded names. A label may use any of them.
E number
- E405
INS number
- 405
CAS registry number
- 9005-37-2
As it appears in regulation
- Propane-1, 2-diol alginate
- Propylene glycol alginate
Other names
- E 405
- Propane-1, 2-diol alginate
- PROPYLENE GLYCOL ALGINATE
Hazard reference values
The two committees set different figures. EFSA's acceptable daily intake is 55 mg/kg bw/day (2018); JECFA's is 70 mg/kg bw/day (1993). An acceptable daily intake is a reference value set by a committee, not a threshold above which harm begins. The lower figure is not a finding that the other body was wrong: the two work to different terms of reference, on their own timetables, and sometimes from different data. This site states both and chooses between them nowhere. See where the two committees differ.
Evidence and how bodies read it
What assessing bodies concluded
Each conclusion is paraphrased in the body's own framing, from the published opinion linked beneath it. Where bodies differ, both stand; this site does not adjudicate between them or add a view of its own.
EFSA 2018
The ANS Panel considered that any adverse effect of propane-1,2-diol alginate (E 405) would be due to propane-1,2-diol and, on that basis, allocated an ADI of 55 mg/kg bw/day. Exposure did not exceed the ADI in any population group, and it concluded there is no safety concern at authorised use levels.
Common questions
Assembled from what is above, in the words the questions are usually asked in. Each answer is the same statement the relevant section makes, with the same citations behind it.
- What is E 405?
- E 405 is Propylene glycol alginate. Propylene glycol alginate is an alginate modified to survive acid, which makes it the thickener of choice for salad dressings and for stabilising beer foam.
- What is Propylene glycol alginate used for in food?
- It is listed as an emulsifier, a thickener and a stabiliser — the role Canada, Codex and the US assign it. This page shows every function each regulator records, with the citation for each.
- Where is Propylene glycol alginate permitted?
- Of the seven regulators this site reads, Australia and New Zealand, Canada, the EU, Great Britain, Japan, South Korea, the US and the Codex standard permit it. Each permission is for named foods at named levels, not a blanket one; the table on this page gives them with citations.
- Is Propylene glycol alginate vegan?
- Yes. Propylene glycol alginate is not derived from animals, and is suitable for vegetarians. This page says what it is made from and how.
Sources for this page
- anz retrieved 2026-10-17
- ca retrieved 2026-10-17
- eu retrieved 2026-10-18
- gb retrieved 2026-10-18
- jp retrieved 2026-10-18
- kr retrieved 2026-10-18
- ecfr retrieved 2026-10-17
- gsfa retrieved 2026-09-07
- euspecs retrieved 2026-10-18
- jecfaspecs retrieved 2026-09-23
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